清華大學材料科學與工程研究院《材料科學論壇》學術報告

報告時間：2024年10月28日上午10:30

報告人：Dr. Hua Zhang (Director of Hong Kong Institute for Clean Energy)

報告地點：清華大學逸夫技術科學樓A512會議室

邀請人：林元華老師

報告題目：Phase Engineering of Nanomaterials (PEN)

報告簡介：

In this talk, I will summarize the recent research on phase engineering of nanomaterials (PEN) in my group, particularly focusing on the rational design and synthesis of novel nanomaterials with unconventional phases for various promising applications. For example, by using wet-chemical methods, for the first time, we have successfully prepared novel Au nanostructures (e.g., the hexagonal-close packed (hcp) 2H-Au nanosheets, 4H-Au nanoribbons, and crystal-phase heterostructured 4H/fcc and fcc/2H/fcc heterophase Au nanorods), epitaxially grown metal nanostructures on the aforementioned unconventional Au nanostructures and 2H-Pd nanoparticles, and amorphous/crystalline heterophase Pd, PdCu, Rh and Rh alloy nanosheets. By using gas-solid reactions, metastable 1T'-phase group VI transition metal dichalcogenides (TMDs), e.g., WS2, WSe2, MoS2, MoSe2, WS2xSe2(1-x) and MoS2xSe2(1-x), have been prepared. Impressively, the 1T'-MoS2-supported single-atomically dispersed Pt (s-Pt) atoms with Pt loading up to 10 wt% exhibit superior performance in hydrogen evolution reaction. Importantly, 1T'-TMD monolayers can be stabilized on 4H-Au nanowires, which can be used for ultrasensitive SERS detection Moreover, the salt-assisted 2H-to-1T' phase transformation of TMDs have been achieved, and the phase transformation of TMDs during our developed electrochemical Li-intercalation process has been observed. Impressively, the lithiation-induced amorphization of Pd3P2S8 has been achieved. Currently, my group focuses on the investigation of phase-dependent physicochemical properties and applications in catalysis, (opto-)electronic devices, clean energy, chemical and biosensors, surface enhanced Raman scattering, photothermal therapy, etc., which we believe is quite unique and very important not only in fundamental studies, but also in future practical applications. Importantly, the concepts of phase engineering of nanomaterials (PEN), crystal-phase heterostructures, and heterophase nanomaterials are proposed.

報告人簡介：

Dr. Hua Zhang obtained his B.S. and M.S. degrees at Nanjing University in China in 1992 and 1995, respectively, and completed his Ph.D. with Prof. Zhongfan Liu at Peking University in China in July 1998. In 2019, he joined the Department of Chemistry in City University of Hong Kong as a Chair Professor, and currently he is the Herman Hu Chair Professor of Nanomaterials and the Director of Hong Kong Institute for Clean Energy. He has published 8 invited book chapters, over 100 patent applications, and over 500 papers including those published in Nature, Science, Nat. Mater., etc. As at August 2024, the total cited times are over 132,200 with H-index of 181. He was elected as a Foreign Fellow of the European Academy of Sciences, an Academician of the Asia Pacific Academy of Materials (APAM), and a Fellow of the Royal Society of Chemistry (FRSC). His current research interests focus on phase engineering of nanomaterials (PEN) and controlled epitaxial growth of heterostructures.