1. 研究成果
(1) 提出了釋放高價反離子直接成型新工藝,發明了若幹種陶瓷濃懸浮體凝固方法,闡明了釋放高價反離子在第一極小值固化機制,使陶瓷材料韋伯模數大幅度提高(20-40)。
(2) 通過降低分散劑的分散性能,使陶瓷濃懸浮體Zeta電位降低從而實現原位凝固的方法,成功制備了高可靠性複雜形狀的陶瓷部件和材料。
(3) 采用顆粒穩定泡沫技術結合噴霧幹燥法,成功制備了工業固體廢棄物開孔和閉孔空心微珠。閉孔陶瓷微珠具有輕質、保溫隔熱功能,成功制備了容重0.1 g/cm3、導熱系數0.027 W/mK 的A1級無機防火保溫材料。開孔陶瓷空心微珠濾料具有優異的吸附和過濾性能;能夠脫色、除異味;可顯著降低COD/BOD,在解決大宗工業固體廢棄物排放、污水治理、海綿城市建設和土壤修複等領域提出一種以廢治廢,變廢為寶,環境友好、綠色發展循環經濟新模式。
(4) 提出膠态成型制備避免應力坯體及方法的學術思想。該學術思想指出:膠态原位凝固成型雖然可以獲得密度均勻的坯體,但在液固轉變過程中容易産生内應力,内應力将會在幹燥、排膠、燒結和機加工的過程中發展、遺傳和變異,并且指出克服坯體的内應力将是今後陶瓷膠态成型工藝重要的發展方向。
(5) 發明了高性能陶瓷微珠(0.1-3 mm)普适性的制備方法和裝備,建立了一條年産5000噸陶瓷微珠磨介生産線,2005年該項目被世界500強法國聖戈班收購,為地方經濟做出突出貢獻。将氧化锆陶瓷球珠應用到制筆行業,提高書寫壽命5倍以上,被列為中國制筆行業協會十一五重點推廣項目,整體提升了我國制筆行業水平。
2. 代表性學術文章
(1) W. Huo, X. Zhang, E. Tervoort, S. Gantenbein, J. Yang, A. R. Studart. Ultrastrong hierarchical porous materials via colloidal assembly and oxidation of metal particles. Advanced Functional Materials. 2020, 2003550.
(2) Jingjing Liu, Bo, Ren, Yuju Lu, Yedong Rong, Chao Wang, Lu Wang, Jinlong Yang, Yong Huang. Mechanically robust ZrO2 foams with 3D reticular architecture prepared from chemical-modified ZrO2 powder. Journal of the American Ceramic Society. 2020, 103(8): 4548−4557.
(3) Jingjing Liu, Bo Ren, Yedong Rong, Yi Zhao, Lu Wang, Yuju Lu, Chao Wang, Guolong Sang, JinlongYang. Highly porous alumina cellular ceramics bonded by in-situ formed mullite prepared by gelation-assisted Al2O3–Si particle-stabilized foams. Ceramics International. 2020, 46(8): 12282-12287.
(4) JingjingLiu, Bo Ren, Kele Liu, Man Yu, Xinglin Li, Zhaoqing Wang, Lu Wang, Jinlong Yang, Yong Huang. Highly porous SiC cellular ceramics for efficient high-temperature PM removal. Ceramics International, 2020, 46(10): 15249-15254.
(5) Jingjing Liu, Bo Ren, Yedong Rong, Yuju Lu, Yi Zhao, Lu Wang, Xiaoqing Xi, Jinlong Yang, Yong Huang. Ultralight and mechanically robust SiC foams with interconnected cellular architecture. Ceramics International, 2020, 46(11): 17962-17968.
(6) J. Liu, H. Yang, B. Ren, Y. Rong, X. Xi, Y. Lu, Y. Zhao, and J. Yang. Highly porous ZrO2 cellular ceramics with 3D network architecture. Ceram. Int., 2020, 46(6): 7149-7154.
(7) K. Gan, Y. Lu, J. Wu, X. Zhang, Y. Wang, B. Ren, W. Huo, Y. Chen, J. Yang. In situ coagulation of yttria-stabilized zirconia ceramic with enhancement of green body via polyvinyl pyrrolidone crosslink. J. Appl. Polym. Sci, 2020, 48889: 1-8.
(8) K.Gan ,Y. Gai. Y. Wang J. Cui Y. Lu X. Zhang. J. Liu. J. Xu. J. Yang. Direct coagulation casting of silicon carbide suspension via polyelectrolyte dispersant crosslink reaction Int. J. Appl. Ceram. Technol. 2020, 17: 274–284.
(9) Y. Lu, K. Gan, J. Liu, B. Ren, X. Zhang, Y. Rong, J. Xu, J. Yang, Gelcasting of alumina via cross-linking of a polyelectrolyte dispersant, Ceramics International, 2020, 46(6): 8308–8313.
(10) Y. Lu, J. Liu, B. Ren, C. Wang, Y. Rong, K. Gan, J. Xu, J. Yang. Room-temperature gelcasting of alumina with tartaric acid and glutaraldehyde. Ceramics International, 2020, 46(8, Part A): 11432–11435.
(11) B. Ren, J. Liu, Y. Rong, L. Wang, Y. Lu, X. Xi, J. Yang. Nanofibrous aerogel bulk assembled by cross-linked SiC/SiOx core−shell nanofibers with multifunctionality and temperature-invariant hyperelasticity. ACS Nano, 2019, 13(10): 11603−11612.
(12) B. Ren, J. Liu, Y. Wang, X. Xi, Y. Lu, R. Yedong, L. Wang, Y. Chen, J. Yang. Highly porous and hierarchical MgAl2O4 ceramics with improved pore connectivity prepared from gelled particle-stabilized foams. Ceram. Int., 2019, 45(14): 17489-17494.
(13) B. Ren, J. Liu, Y. Wang, Y. Chen, K. Gan, Y. Rong, J. Yang. Hierarchical cellular scaffolds fabricated via direct foam writing using gelled colloidal particle-stabilized foams as the ink. J. Am. Ceram. Soc.,2019, 102(11): 6498-6506.
(14) B. Ren, J. Liu, W. Huo, K. Gan, S. Yan, Y. Chen, Y. Lu, J. Yang, Y. Huang. Three-dimensional (3D) flexible nanofibrous network knitting on hierarchical porous architecture. J. Am. Ceram. Soc., 2019, 102(5): 2977-2986.
(15) B. Ren, Y. Wang, J. Liu, X. Zhang, Y. Chen, Y. Rong and J. Yang. Preparation of Al2O3-Si3N4 porous ceramics with a cactus-like architecture for potential filters applications. Ceram. Int., 2019, 45(5): 6581-6584.
(16) B. Ren, J. Liu, W. Huo, K. Gan, Y. Lu, Y. Chen, L. Wang, J. Yang and Y. Huang. Facile fabrication of nanofibrous network reinforced hierarchical structured porous Si3N4-based ceramics based on Si-Si3N4 binary particle-stabilized foams. Ceram. Int., 2019, 45(2): 1984-1990.
(17) J. Liu, B. Ren, S. Zhang, Y. Lu, Y. Chen, L. Wang, J. Yang, and Y. Huang. Hierarchical ceramic foams with 3D interconnected network architecture for superior high-temperature particulate matter capture. ACS. Appl. Mater. Interfaces., 2019, 11: 40585-40591.
(18) J. Liu, B. Ren, Y. Wang, Y. Lu, L. Wang, Y. Chen, J. Yang, and Y. Huang. Hierarchical porous ceramics with 3D reticular architecture and efficient flow-through filtration towards high-temperature particulate matter capture. Chem. Eng. J., 2019, 362: 504-512.
(19) J. Liu, B. Ren, Y. Chen, Y. Lu, S. Zhang, Y. Rong, and J. Yang. Novel design of alumina foams with three-dimensional reticular architecture for effective high-temperature particulate matter capture. J. Am. Ceram. Soc., 2019, 102(9): 5576-5586.
(20) J. Liu, B. Ren, Y. Lu, X. Xi, Y. Li, K. Liu, J. Yang, and Y. Huang. Novel design of elongated mullite reinforced highly porous alumina ceramics using carbonized rice husk as pore-forming agent. Ceram. Int., 2019, 45: 13964-13970.
(21) Lu Y, Gan K, Xu J, et al. Dispersion and gelation properties of alumina systems with Isobam assisted by dicarboxylic acids. Ceramics International, 2019, 45(9): 11939–11945.
(22) Y. Chen, W. Huo, X. Zhang, Y. Lu, S. Yan, J. Liu, K. Gan, and J. Yang. Ultrahigh-Strength Alumina Ceramic Foams via Gelation of Foamed Boehmite Sol. J. Am. Ceram. Soc., 2019, 102(9): 5503-5513.
(23) Shu Yan, Fanyong Zhang, Jingjing Liu, Bo Ren, Peigang He, Dechang Jia, Jinlong Yang. Green synthesis of high porosity waste gangue microsphere/geopolymer composite foams via hydrogen peroxide modification. Journal of Cleaner Production, 2019, 227: 483-494.
(24) Shu Yan, Qinggang Wang, Fanyong Zhang, Xiaoyan Zhang, Yuju Lu, Ke Gan, Wenlong Huo, Shuhao Zhang, Jingjing Liu, Jinlong Yang. Low-cost, green synthesis and adsorption properties for dyes of novel porous gangue/palygorskite composite microspheres. International Journal of Applied Ceramic Technology, 2019, 16(4): 1510-152.
(25) Shu Yan, Qinggang Wang, Jingjing Liu, Wenlong Huo, Jinlong Yang, Yong Huang. Synthesis, Characterization and Adsorption Properties of Low-cost Porous Calcined Dolomite Microspheres for Removal of Dyes. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2019, 34(3): 507-515.
(26) W. Huo, X. Zhang, K. Gan, Y. Chen, Y. Lu, J. Xu, J. Yang. Effect of zeta potential on properties of foamed suspension. Journal of the European Ceramic Society, 2019, 39(2-3):574-538.
(27) W. Huo, X. Zhang, Y. Chen, Z. Hu, D. Wang, J. Yang, Ultralight and high-strength bulk alumina/zirconia composite ceramic foams through direct foaming method, Ceramic International, 2019, 45(1):1464-1467.
(28) W. Huo, X. Zhang, K. Gan, H. Li, S. Yan, Y. Chen, J. Yang. Ceramic particle-stabilized foams/emulsions with UV light response and further synthesis of ceramic capsules, Chemical Engineering Journal. 2019, 360:1458-1467.
(29) W. Huo, X. Zhang, Z. Hu, Y. Chen, Y. Wang, J. Yang. Silica foams with ultra-large specific surface area structured by hollow mesoporous silica spheres. Journal of the American Ceramic Society. 2019, 102(3): 955-961.
(30) W. Huo, X. Zhang, S. Hou, Y. Chen, Y. Wang, J. Yang. Aerogel-like Ceramic Foams with Super-high Porosity and Nanoscale Cell Wall from Sol Nanoparticles Stabilized Foams. Journal of the American Ceramic Society. 2019, 102(6): 3753-3762.
(31) W. Huo, X. Zhang, J. Xu, Z. Hu, S. Yan, K. Gan, J. Yang. In-situ synthesis of three-dimensional nanofiber-knitted ceramic foams via reactive sintering silicon foams, Journal of the American Ceramic Society. 2019, 102(5): 2245-2250.
(32) W. Huo, X. Zhang, B. Ren, J. Liu, D. Wang, J. Yang. Preparation of ultra-stable foams stabilized by large-size platelet particles via direct foaming method. Journal of Ceramic Science and Technology, 2019, 10(1): 39-43.
(33) X. Zhang, W. Huo, Y. Chen, Z. Hu, Y. Wang, K. Gan, J. Yang. Novel micro-spherical Si3N4 nanowire sponges from carbon-doped silica sol foams via reverse templating method, J. Am. Ceram. Soc. 2019, 102(3): 962-969.
(34) X. Zhang, W. Huo, K. Gan, Y. Wang, Z. Hu, J. Yang. Si3N4 hollow microsphere toughened porous ceramics from direct coagulation method via dispersant reaction. Adv. Eng. Mater.. 2019, 21(3): 1800858.
(35) X. Zhang, W. Huo, Y. Lu, K. Gan, S. Yan, J. Liu, J. Yang. Porous Si3N4-based ceramics with uniform pore structure originated from single-shell hollow microspheres. J. Mater. Sci., 2019, 54: 4484-4494.
3. 專著
黃 勇,楊金龍 著,《Novel colloidal forming of ceramics》(第一版),Springer出版社和清華大學出版社聯合出版(全英文專著),2010。
楊金龍,黃 勇 著,《Novel colloidal forming of ceramics》(第二版),Springer出版社和清華大學出版社聯合出版(全英文專著),2020。
楊金龍,許傑,幹科,《陶瓷濃懸浮體新型固化技術及其原理》,清華大學出版社,2020
楊金龍,席小慶,黃 勇 著,《陶瓷微珠》,清華大學出版社;2017。
黃 勇,楊金龍,汪長安 編著,《無機非金屬材料題解指南》,清華大學出版社,2017。
4. 代表性授權專利
(1) 楊金龍, 幹科, 楊潔, 等. 一種碳納米管/陶瓷基複合材料的制備方法: 中國發明專利, 專利号: 201910116646.9. 授權日期: 2020-12-08
(2) 楊金龍, 張在娟, 唐欣悅, 等. 一種利用水性聚氨酯增強超輕泡沫陶瓷坯體強度的方法: 中國發明專利, 專利号: 201711116601.9. 授權日期: 2020-07-07
(3) 楊金龍, 霍文龍, 陳雨谷, 等. 一種以廢玻璃為原料制備微米級氣孔結構可調的泡沫玻璃的方法: 中國發明專利, 專利号: 201710334878.2. 授權日期: 2020-08-21
(4) 楊金龍, 霍文龍, 張笑妍, 等. 一種增強超輕泡沫陶瓷坯體強度的方法: 中國發明專利, 專利号: 201710352108.0. 授權日期: 2020-01-21
(5) 楊金龍, 霍文龍, 張笑妍, 等. 一種利用中空微球制備具有連通孔壁泡沫陶瓷的方法: 中國發明專利, 專利号: 201810883586.9. 授權日期: 2020-08-25
(6) 楊金龍, 霍文龍, 張笑妍, 等. 一種制備泡沫氧化鋁和泡沫鋁/氧化鋁複合材料的方法: 中國發明專利, 專利号: 201810384689.0. 授權日期: 2020-12-15
(7) 楊金龍, 霍文龍, 張笑妍, 等. 一種反向模闆法制備納米線編織微球的陶瓷海綿材料方法: 中國發明專利, 專利号: 201810883488.5. 授權日期: 2020-08-14
(8) 楊金龍, 闫姝, 王璐, 等. 煤矸石空心微珠/鋁矽酸鹽聚合物複合吸附劑及其制備方法: 中國發明專利, 專利号: 201810229119.4. 授權日期: 2020-08-21
(9) 楊金龍, 張在娟, 唐欣悅, 等. 一種基于敲擊聲波法的天線罩無損檢測裝置與方法: 中國發明專利, 專利号: 201810238899.9. 授權日期: 2020-10-27
(10) 楊金龍,霍文龍, 林鴻福, 等. 具有保溫性能的日用多孔複合陶瓷及其制備方法: 中國發明專利, 專利号: 201610850059.9. 授權日期:2019-10-11
(11) 楊金龍, 張笑妍, 李娜,等,一種多孔石英陶瓷的制備方法.中國發明專利,專利号:201610056581.X,授權日期:2018-12-18
(12) 楊金龍,李志君,蘇振國,等,一種以空心微珠為原料的陶粒及其制備方法.中國發明專利,專利号:201610219693.2,授權日期:2018-06-05
(13) 楊金龍, 馬甯, 張月, 等. 一種一步法制備的有序介孔有機氧化矽空心球及其制備方法. 中國發明專利, 專利号: 201510427967.2, 授權日期: 2017-03-01
(14) 楊金龍, 馬甯, 張月, 等. 一種易溶解的氧化矽球、其制備方法及應用. 中國發明專利, 專利号: 201510428142.2, 授權日期: 2017-04-12
(15) 楊金龍, 許傑, 楊名昊, 等. 一種聚磷酸鹽螯合物控釋高價反離子固化陶瓷漿料的方法. 中國發明專利, 專利号: 201510170233.0, 授權日期: 2017-04-12
(16) 楊金龍, 渠亞男, 席小慶, 等. 一種測試高溫發泡過程的方法. 中國發明專利,專利号: 201510065287.0, 授權日期: 2017-08-11
(17) 楊金龍, 陳金德, 席小慶, 等. 一種無機微球快速燒結的方法與裝置. 中國發明專利.專利号: 201310528555.9, 授權日期: 2016-03-09
(18) 楊金龍, 齊飛, 許傑, 等. 一種超輕質閉孔陶瓷的制備方法. 中國發明專利.專利号: 201410253455.4, 授權日期: 2016-06-15
(19) 楊金龍, 蘇振國, 席小慶, 等. 一種利用煤矸石空心微珠自發泡制備無機泡沫材料的方法, 中國發明專利, 專利号: 201310132817.X, 授權日期: 2016-05-11
(20) 楊金龍, 蘇振國, 席小慶, 等. 一種利用廢玻璃制備微孔泡沫玻璃的方法. 中國發明專利, 專利号: 201310529973.X, 授權日期: 2015-12-09
(21) 楊金龍, 吳甲民, 張笑妍, 等. 一種采用陶瓷空心球制備多孔陶瓷的方法. 中國發明專利, 專利号: 201310430728.3, 授權日期: 2015-10-28
(22) 楊金龍, 許傑, 渠亞男, 等. 通過緩慢調節pH值控制高價反離子固化陶瓷漿料的方法. 中國發明專利, 專利号: 201410009146.2, 授權日期: 2015-4-15
(23) 楊金龍, 許傑, 渠亞男, 等. 一種非氧化物陶瓷的直接凝固注模成型方法. 中國發明專利, 專利号: 201410130619.4, 授權日期: 2015-4-15
(24) 楊金龍, 申殿軍, 席小慶, 等. 運動員力竭運動後快速恢複系統. 中國發明專利, 專利号: 201210525897.0, 授權日期: 2015-07-08
(25) 楊金龍, 許傑, 溫甯, 等. 一種溫度控制高價反離子緩釋固化陶瓷漿料的方法. 中國發明專利, 專利号: 201110291426.3, 授權日期: 2014-01-01
(26) 楊金龍, 蘇振國, 席小慶, 等. 一種具有二級閉孔結構的無機保溫材料及其制備方法. 中國發明專利, 專利号: 201210282748.6, 授權日期: 2014-06-25
(27) 楊金龍, 溫甯, 許傑, 等. 一種通過緩釋高價反離子實現陶瓷漿料直接凝固成型的方法. 中國發明專利, 專利号: 201110140027.7, 授權日期: 2014-09-17
(28) 楊金龍, 蘇振國, 席小慶, 等. 一種具有三級孔結構的無機保溫材料及其制備方法. 中國發明專利, 專利号: 201210592778.7, 授權日期: 2014-09-24
(29) 楊金龍, 馬甯, 龍夢龍, 等. 一種微米級蜂窩陶瓷及其孔徑和孔壁尺寸的調控方法. 中國發明專利, 專利号: 201310164617.2, 授權日期: 2014-09-24